CONTENTS

PlasmonExciton Interaction： Principlesand Applications
CONTENTS
CHAPTER 1Introduction

References

CHAPTER 2PlasmonDrivenChemical Reactions Based on
SERS in Atmosphere
2.1Brief introduction

2.2Plasmondriven oxidationreactions<p> </p> <p>CONTENTS</p> <p> </p> <p>PlasmonExciton Interaction： Principles and Applications</p> <p>CONTENTS</p> <p>CHAPTER 1Introduction</p> <p> </p> <p>References</p> <p> </p> <p>CHAPTER 2PlasmonDriven Chemical Reactions Based on </p> <p>SERS in Atmosphere</p> <p>2.1Brief introduction</p> <p> </p> <p>2.2Plasmondriven oxidation reactions</p> <p> </p> <p>2.2.1Genuine SERS spectrum of PATP</p> <p> </p> <p>2.2.2Experimental and theoretical investigations of </p> <p>plasmondriven oxidation reactions</p> <p> </p> <p>2.3Plasmondriven reduction reactions</p> <p> </p> <p>2.4Priority between plasmondriven oxidation and </p> <p>reduction reactions</p> <p> </p> <p>References</p> <p> </p> <p>CHAPTER 3PlasmonDriven Surface Catalytic Reactions Monitored by </p> <p>Electrochemical SERS in Liquid</p> <p>3.1Introduction </p> <p> </p> <p>3.2Designed apparatus</p> <p> </p> <p>3.3Plasmondriven reduction reactions in liquid</p> <p> </p> <p>3.3.1Laserintensitydependent</p> <p> </p> <p>3.3.2Potentialdependent</p> <p> </p> <p>3.3.3LSPRdependent</p> <p> </p> <p>3.3.4pHdependent</p> <p> </p> <p>3.4Plasmondriven oxidation reactions</p> <p> </p> <p>3.5Priority between plasmondriven surface catalytic </p> <p>reactions in liquid</p> <p> </p> <p>References</p> <p> </p> <p>CHAPTER 4PlasmonDriven Surface Catalysis Reactions Monitored by </p> <p>TERS in High Vacuum</p> <p>4.1Introduction of TERS</p> <p> </p> <p>4.2Brief history of TERS</p> <p> </p> <p>4.3Setup of TERS</p> <p> </p> <p>4.4Plasmondriven surface catalytic reactions</p> <p> </p> <p>References</p> <p> </p> <p>CHAPTER 5PlasmonExciton CoDriven Surface Catalytic Reactions</p> <p> </p> <p>5.1Introduction</p> <p> </p> <p>5.2Mechanisms </p> <p> </p> <p>5.2.1Free space spontaneous emission</p> <p> </p> <p>5.2.2Spontaneous emission in cavities</p> <p> </p> <p>5.3Femtosecond absorption</p> <p> </p> <p>5.4Applications </p> <p> </p> <p>References</p> <p> </p> <p>CHAPTER 6PlasmonExciton CoDriven Catalytic Reactions Based on </p> <p>Electrochemical SERS</p> <p>6.1Introduction </p> <p> </p> <p>6.2Plasmonexciton codriven reduction reactions</p> <p> </p> <p>6.3Plasmonexciton codriven oxidation reactions</p> <p> </p> <p>6.4The priority in the plasmonexciton codriven </p> <p>catalytic reactions</p> <p> </p> <p>6.5Conclusions</p> <p> </p> <p>References</p> <p> </p> <p>CHAPTER 7ElectroOptical Synergy on PlasmonExciton CoDriven Surface </p> <p>Reduction Reactions</p> <p>7.1Introduction</p> <p> </p> <p>7.2Properties of electrooptical device</p> <p> </p> <p>7.2.1Optical measurements</p> <p> </p> <p>7.2.2Electrical measurements</p> <p> </p> <p>7.3Plasmonexciton codriven surface reduction reactions</p> <p> </p> <p>7.3.1Laser intensitydependent surface reduction </p> <p>reactions</p> <p> </p> <p>7.3.2Biasvoltagedependent surface reduction reaction</p> <p> </p> <p>7.3.3Gatevoltagedependent surface reduction reaction</p> <p> </p> <p>References</p> <p> </p> <p>Acknowledgements</p> <p> </p> <p> </p> <p> </p>显示全部信息免费在线读

CHAPTER 1Introduction
In this book,from principles to applications,we introduce plasmondriven and plasmonexciton codriven surface catalytic reactions in atmosphere,liquid and high vacuum environments.Since the discovery of plasmondriven chemical reaction in 2010［1,2］,plasmonic chemistry has been one of important branches of plasmonics［3,4］.While,the lifetime of plasmonic hot electrons generated from plasmon decay is about 150 femtoseconds,which is too short to surface catalytic reaction,and then the probability and efficiency of plasmondriven chemical reactions are low.To increase them,the lifttime and amounts of plasmonic hot electrons should be significantly increased.
The plasmonexciton coupling interaction for surface catalytic reactions has been reported in 2015,in which the probability and efficiency of plasmonexciton codriven chemical reactions have been significantly increased,where the lifetime of hot electrons has been enlarged to several hundred picoseconds［58］.The ultrafast femtosecond pumpprobe absorption spectroscopy reveals the nature of plasmonexcition coupling interactions,and demonstrates the ultrafast electron transfer between the plasmon metal and the exciton semiconductor.
To further improve the probability and efficiency of plasmonexciton codriven chemical reactions,the gate voltage and the bias voltage and current have also been employed by us.The electrooptical synergy has been applied in plasmonexcitoncodriven surface reduction reactions in 2017［9］.The voltage manipulates plasmonexciton codriven chemical reactions can reach up to higher probability and efficiency in surface catalytic reactions.
In this book,we introduce plasmonic chemistry in the field of surface catalytic reactions in detail,including the principles and applications of interactions among plasmon,exciton and molecule on the plasmonic nanostructure covered by monolayer semiconductors.The book is suitable for the research scientists,Ph.D.candidates and bachelor students,who would like to learn or study plasmonexciton codriven chemical reactions.

CONTENTS

PlasmonExciton Interaction： Principlesand Applications
CONTENTS
CHAPTER 1Introduction

References

CHAPTER 2PlasmonDrivenChemical Reactions Based on
SERS in Atmosphere
2.1Brief introduction

2.2Plasmondriven oxidationreactions

等离激元－激子相互作用：原理和应用在介绍经典的理论解释和应用时加入大量科研*前沿的进展，保证读者在能理解基础概念的同时，对本领域的发展进展和热点有一定了解。